期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 404, 期 -, 页码 368-371出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2004.12.164
关键词
X-ray diffraction; high pressure
The decomposition pressure P-dec of copper deuteride has been experimentally determined in a diamond anvil cell. The value of 6.8 +/- 0.6 GPa is lower than the corresponding pressure of copper hydride. The difference between standard Gibbs energies of decomposition of copper hydride and deuteride has been calculated as equal to -5.2 kJ mol(-1) (H-2). The zero-point energy of hydrogen vibration in the hydride lattice has been obtained applying the localized harmonic oscillator model. (c) 2005 Elsevier B.V. All rights reserved.
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