We present a rigorous theoretical study of the solvation of (HCl)(2) and (HF)(2) by small (He-4)(n) clusters, with n=1-14 and 30. Pairwise-additive potential-energy surfaces of He-n(HX)(2) (X=Cl and F) clusters are constructed from highly accurate four-dimensional (rigid monomer) HX-HX and two-dimensional (rigid monomer) He-HX potentials and a one-dimensional He-He potential. The minimum-energy geometries of these clusters, for n=1-6 in the case of (HCl)(2) and n=1-5 for (HF)(2), correspond to the He atoms in a ring perpendicular to and bisecting the HX-HX axis. The quantum-mechanical ground-state energies and vibrationally averaged structures of He-n(HCl)(2) (n=1-14 and 30) and He-n(HF)(2) (n=1-10) clusters are calculated exactly using the diffusion Monte Carlo (DMC) method. In addition, the interchange-tunneling splittings of He-n(HCl)(2) clusters with n=1-14 are determined using the fixed-node DMC approach, which was employed by us previously to calculate the tunneling splittings for He-n(HF)(2) clusters, n=1-10 [A. Sarsa , Phys. Rev. Lett. 88, 123401 (2002)]. The vibrationally averaged structures of He-n(HX)(2) clusters with n=1-6 for (HCl)(2) and n=1-5 for (HF)(2) have the helium density localized in an effectively one-dimensional ring, or doughnut, perpendicular to and at the midpoint of the HX-HX axis. The rigidity of the solvent ring varies with n and reaches its maximum for the cluster size at which the ring is filled, n=6 and n=5 for (HCl)(2) and (HF)(2), respectively. Once the equatorial ring is full, the helium density spreads along the HX-HX axis, eventually solvating the entire HX dimer. The interchange-tunneling splitting of He-n(HCl)(2) clusters hardly varies at all over the cluster size range considered, n=1-14, and is virtually identical to that of the free HCl dimer. This absence of the solvent effect is in sharp contrast with our earlier results for He-n(HF)(2) clusters, which show a similar to 30% reduction of the tunneling splitting for n=4. A tentative explanation for this difference is proposed. The implications of our results for the interchange-tunneling dynamics of (HCl)(2) in helium nanodroplets are discussed. (c) 2005 American Institute of Physics.
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