We report an ab initio-based global potential energy surface for H+CH4 that describes the abstraction and exchange reactions. The PES, which is invariant with respect to any permutation of five H atoms, is a fit to 20 728 electronic energies calculated using the partially spin-restricted coupled-cluster method (RCCSD(T)) with a moderately large basis (aug-cc-pVTZ). A first set of quasiclassical trajectory calculations using this PES are reported for the H+CD4 -> HD+CD3 reaction at collision energies of 0.65 and 1.52 eV and are compared to experiment and recent direct dynamics calculations done with density functional theory. (c) 2006 American Institute of Physics.
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