期刊
ORGANIC LETTERS
卷 8, 期 2, 页码 251-254出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol052589i
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资金
- NIGMS NIH HHS [R01 GM018754-46] Funding Source: Medline
A novel catalyst has been synthesized in which a manganese-porphyrin unit is linked to two 2,2 '-bipyridyl groups and two pentafluorophenyl groups in trans fashion on its four meso positions. Relative to a previous catalyst in which the manganese-porphyrin had four 2,2 '-bipyridyl groups, the new catalyst, in the presence of Cu2+ ions as coordinating linkers, catalyzes the oxidation of a steroid substrate with much better regioselectivity and higher turnover numbers.
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