期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 207, 期 2, 页码 160-165出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200500436
关键词
emulsion polymerization; lanthanide complexes; miniemulsion; nanocomposites; self-organization
The addition of neutral, inert inner shell lanthanide complexes such as Gd(III)-(tmhd)(3), Eu(III)-(fod)(3), or Ho(III)-thmd(3), broadly available as NMR shift reagents, towards ester-containing monomers such as butyl acrylate and subsequent polymerization in miniemulsion droplets leads to the spontaneous formation of highly organized layered nanocomposite particles, as revealed by electron microscopy and small angle X-ray scattering. The nanocomposite comprises a lanthanide complex phase and a polymer phase with a lamellar repeat period of about 3.5 nm, rather independent of the system composition.
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