期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 12, 期 4, 页码 975-979出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200500466
关键词
carbonyl compounds; cycloaddition; fluorine; Michael addition
beta-Fluoroalkylated alpha,beta-unsaturated carbonyl compounds constitute efficient building blocks for the synthesis of complex fluorinated compounds. As the fluorinated moiety generally increases their reactivity, it also brings important modifications which can change the chemical behavior and selectivity. Their use has been already largely demonstrated. Nevertheless, the synthetic potential has not yet been fully explored and, consequently should play an important role in the design of new sophisticated fluorinated molecules. Nevertheless, it shall be important to develop new synthetic methods to enlarge their availability and their diversity.
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