期刊
CHEMISTRY OF MATERIALS
卷 18, 期 2, 页码 321-327出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm051659c
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- Engineering and Physical Sciences Research Council [EP/D502012/1] Funding Source: researchfish
Reaction of the n = 2 Ruddlesden-Popper phase YSr2Mn2O7 with NaH at 225 degrees C yields the topotactically reduced phase YSr2Mn2O5.43(3) (a = 3.62043(4) angstrom, c = 22.3570(3) angstrom). Combination of this reduced phase with the stoichiometric starting material at 400 degrees C yields intermediate phases:YSr2Mn2O6.54(3) (a = 3.80900(7) angstrom, c = 20.2691(5) angstrom) and YSr2Mn2O5.96(3) (a = 3.81071(7) angstrom, c = 20.5238(4) angstrom). The variation in the anion vacancy distribution of these reduced phases as a function of stoichiometry is discussed in relation to the coordination polyhedra of the metal cations. Temperature-dependent magnetization data indicate strong antiferromagnetic coupling interactions in all samples. Long-range magnetic order is suppressed by structural or charge disorder in all samples except YSr2Mn2O5.5, which adopts a G-type antiferromagnetic ordering scheme with an ordered moment of 4.61(5)mu(B) per manganese, consistent with S = 5/2 Mn(II).
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