期刊
TETRAHEDRON LETTERS
卷 47, 期 5, 页码 631-634出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.11.121
关键词
indium bromide; indole; intramolecular cyclization; 2-ethynylaniline
We describe InBr3-catalyzed cyclization of 2-alkynylanifine derivatives having a variety of functional groups producing polysubstituted indoles. This methodology could be applied to the one-pot synthesis of an amino acid precursor by the addition of a catalytic amount of the indium salt, an imine, and TMSCI. (c) 2005 Elsevier Ltd. All rights reserved.
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