期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 348, 期 3, 页码 305-308出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505327
关键词
(Z)-alkenes; alkynes; cis-hydrogenation; nanoparticles; nickel; stereoselectivity
A new method for the highly stereoselective cis-semihydrogenation of internal alkynes is described based on in situ generated Ni(0) nanoparticles and molecular hydrogen. This reduction system also allows the semihydrogenation of terminal alkynes.
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