期刊
THIN SOLID FILMS
卷 496, 期 1, 页码 30-36出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2005.08.183
关键词
optoelectronic devices; tungsten oxide; nickel oxide; sputtering
Current work on inorganic electrochromic materials and devices is reviewed briefly, and the emphasis on thin films of W oxide and Ni oxide is pointed out. New results are presented on the optical properties for sputter-deposited thin films of these two materials: for Li+ intercalated substoichiometric W oxide, it is shown that the absorption can be reconciled with an extended site saturation model accounting for electronic transitions between W ions in 6+, 5+, and 4+ states, and for H+ deintercalated Ni oxide, it is found that the coloration efficiency is higher than in prior work presumably as a consequence of the nanocrystalline structure ensuing from the deposition conditions. (c) 2005 Elsevier B.V. All rights reserved.
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