期刊
PURE AND APPLIED CHEMISTRY
卷 78, 期 2, 页码 363-375出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200678020363
关键词
Curtius rearrangement; nitrene; aziridination; C-H insertion; rhodium
Studies regarding the transition-metal-catalyzed decomposition of nitrogen derivatives toward Curtius rearrangement and the formation of nitrenes which undergo C-H insertion and aziridination reactions are presented. These processes lead to the formation of C-N bond with a high level of selectivity and efficiency.
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