期刊
PURE AND APPLIED CHEMISTRY
卷 78, 期 2, 页码 469-476出版社
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/pac200678020469
关键词
catalysis; ruthenium; metathesis; tandem sequence; isomerization
Tandem sequences consisting of an olefin metathesis step and a subsequent non-metathesis reaction become accessible by organometallic transformations of the Ru-carbene species in situ. This contribution highlights some tandem sequences that rely on the conversion of the metathesis catalyst to Ru-hydrides, with special emphasis on the tandem ring-closing metathesis (RCM)-double-bond isomerization sequence.
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