A semi-quantitative standard-less analysis method for laser-induced breakdown spectroscopy

We report on recently developed analytical software to model laser-induced breakdown spectroscopy emission spectra and predict sample composition using a proposed calibration-free algorithm. The model uses a database of atomic emission lines to create a theoretical emission spectrum for selected elements using defined plasma parameters. The resulting theoretical spectrum is fitted to experimental data obtained from a laser-induced breakdown spectroscopy instrument comprising of four compact spectrometers that image the plasma emission. Elemental concentrations are obtained by comparing observed and predicted spectra while varying the plasma temperature and relative elemental concentrations. The use of the model for analysis of major elements in bauxites, brass and mineral samples as well as the analysis of laboratory air is demonstrated. For the majority of elements investigated agreement within 25% is achieved between estimated and certified values. (c) 2006 Elsevier B.V. All rights reserved.