期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 12, 期 6, 页码 1754-1759出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200501061
关键词
porphyrinoids; pyrrole rearrangement; structure elucidation; transition metals
Treatment of hexakis (pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (1) with CuCl in the presence of pyridine and molecular oxygen led to formation of doubly N-confused [26]hexaphyrin(1.1.1.1.1.1) 2 in a moderate yield through an unprecedented double pyrrolic rearrangement. Macrocycle 2 has been shown to serve as an effective bis-metal-coordinating ligand and exhibits attractive optical properties such as a sharp Soret-like band at 566 nm and low-energy fluorescence at 1058 nm.
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