期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 12, 期 6, 页码 1694-1702出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200501089
关键词
alkynes; cyclization; density functional calculations; gold; platinum; zinc
Gold(I) complexes are the most active catalysts for the biscyclopropanation of dienynes to form tetracyclic compounds. Pt-II and Zn-II are also able to promote the biscyclopropanation, although less efficiently. The configurations obtained in all cases with the use of gold(I) catalysts can be explained by the pathway proceeding through anti cyclopropyl gold carbenes. Similar intermediates are most probably involved in reactions catalyzed by Ru-II and Pt-II. Two different cyclopropanation pathways have been found; they depend on the structures of the cyclopropyl gold carbenes (anti or syn) and the relative arrangements of the metal carbenes and the alkenes.
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