期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 95, 期 2-3, 页码 218-221出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2005.06.014
关键词
lithium secondary batteries; layered material; Na doping; sol-gel method
Layered Li1.1-xNax[Ni0.2Co0.3Mn0.4]O-2 (x= 0, 0.05, 0.1 and 0.2) materials with high homogeneity and high crystallinity were prepared by a sol-gel method. Structural and electrochemical properties of the Li1.1-xNax[Ni0.2Co0.3Mn0.4]O-2 materials were characterized by means of powder X-ray diffraction, and galvanostatic charge/discharge cycling. Na-doped samples had a phase-pure layered structure with a space group of R3m (No. 166). Although, the discharge capacity decreased linearly with increases of Na-substitution, only a few of the Na-doped (x = 0.05, 0.1) electrodes exhibited superior rate capability and good capacity retention. (c) 2005 Published by Elsevier B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据