期刊
TALANTA
卷 68, 期 4, 页码 1148-1155出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2005.07.017
关键词
mean centering; ratio kinetic profiles; analysis of ternary mixtures
In this paper, a novel and very simple method was developed for the simultaneous spectrophotometric determination of ternary mixtures, without prior separation steps. The method is based on the mean centering of ratio kinetic profiles. The mathematical explanation of the procedure is illustrated. In order to investigate the applicability of the proposed method, it was applied to the simultaneous spectrophotometric determination of hydrazine, phenylhydrazine and acetylhydrazine based on their condensation reactions with p-(dimethylamino)benzaidehyde (DAB) and p-nitrobenzaidehyde (NB) in micellar sodium dodecyl sulfate (SDS) media as a typical ternary mixture. The analytical characteristics of the method such as accuracy, precision, relative standard deviation (R.S.D.) and relative standard error (R.S.E.) were calculated.(c) 2005 Elsevier B.V. All rights reserved.
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