Reaction between nido-B10H14 (1) and elemental sulfur in CHCl3, in the presence of Et3N at room temperature, followed by treatment with Et3N center dot BH3 at 170-190 degrees C, resulted in the isolation of closo-1-SB11H11 (2) in 50% yield. Selected electrophilic halogenation reactions of compound 2 led to the isolation of a series of monoltalogenated derivatives of general constitution 12-X-closo-1-SB11H10 (12-X-2, where X = Cl, Br, and I). The structures of 12-Cl-2 and 12-I-2 were determined by an X-ray diffraction analysis and the structures of all compounds were geometry optimised at the RMP2(fc)/6-31G* level. The constitution of all compounds is consistent with the results of mass spectrometry and multinuclear (H-1 and B-11) spectroscopy complemented by two-dimensional [B-11-B-11]-COSY and H-1{B-11(selective)} NMR measurements. Experimental B-11 chemical shifts generally show acceptable agreement with theoretical values calculated by GIAO methods, but spin-orbit coupling must be included for nuclei bearing heavy-atom substituents such as Br or I. The dipole moments determined for the B12-X bonds show similarities to those of aliphatic C-X bonds and confirm unambiguously the B12 -> S dipole moment orientation in the SB11 cage.
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