期刊
LETTERS IN ORGANIC CHEMISTRY
卷 3, 期 3, 页码 170-175出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017806775789976
关键词
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Fluorous solvent in phase-vanishing reactions acts as a phase screen between the bulk reagent and the reaction phase. The unique properties of the fluorous phase enable the stow diffusion-controlled transport of reagent through this bulk membrane and its uniform phase-transition from transport to reaction phase. Slow addition through the whole interface prevents the build-up of localised high concentration of reagent which means that it is possible to perform reactions involving highly reactive reagents at room temperature.
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