期刊
CANADIAN JOURNAL OF CHEMISTRY
卷 84, 期 3, 页码 429-432出版社
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/V06-024
关键词
catalyzed Strecker's reaction; alpha-aminonitriles; magnesium bromide; solvent-free
A three-component, efficient, and facile procedure has been developed for the synthesis of alpha-aminonitriles from aldehydes, amines, and trimethylsilyl cyanide using a catalytic amount of magnesium bromide ethyl etherate in the absence of solvent. Rapid formation of products is observed at room temperature in a one-pot procedure under very mild conditions giving excellent yields of the title compounds.
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