期刊
SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 90, 期 4, 页码 422-433出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.solmat.2005.01.018
关键词
Ni-W-O mixed systems; pulsed laser deposition; durability; electrochromism; thin films
Aiming at improving the electrochromic properties of NiO thin films, well-known as anodic counter electrodes, the effect of tungsten addition was investigated. Ni-W-O thin films were deposited by pulsed laser deposition in optimized conditions, namely a 10(-1) mbar oxygen pressure and a room temperature substrate. The presence of W led to a progressive film amorphization. An increase in cyclability for Ni-W-O (5%(t) WO3) electrode, cycled in KOH I M electrolyte, was associated with a limited dissolution of the oxidized phases with tungsten addition. HRTEM investigations of cycled films revealed that the stabilization is correlated to the existence of an alpha(II) hydroxide phase. (c) 2005 Elsevier B.V. All rights reserved.
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