期刊
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
卷 39, 期 5, 页码 R79-R125出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/39/5/R01
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This review covers the outer core level photoionization of the free 3d metal atoms from Sc to Cu. The experimental 3p, 3s and 2p photoemission and photoabsorption spectra are discussed. A comparison emphasizes common features and distinct differences. The interpretation of the data based on ab initio calculations reveals the influence of multi-electron interactions in the 3d metal atoms. We focus on the fundamental effects and main interactions which govern the electronic structure of these open shell atoms.
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