Alumina modified by dimethyl sulfoxide as a new selective solid phase extractor for separation and preconcentration of inorganic mercury(II)

Dimethyl sulfoxide (DMSO) was simply immobilized to neutral alumina via quite strong hydrogen bonding between sulfoxide oxygen and surface alumina hydroxo groups. The produced alumina-modified dimethyl sulfoxide (AMDMSO) solid phase (SP)-extractor experienced high thermal and medium stability. Moreover, the small and compact size of DMSO moiety permit high surface coverage evaluated to be 2.1 +/- 0.1 mmol g(-1) of alumina. Hg(II) uptake was 1.90 mmol g(-1)(distribution coefficient log K-d = 5.658) at pH 1.0 or 2.0, 1.68 mmol g(-1) (log K-d = 4.067) at pH 3.0 or 4.0 while the metal ions Ca(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) showed low values 0.513-0.118 mmol g(-1) (log Kd < 3.0) in the pH range 4.0-7.0. A mechanism was suggested to explain the unique uptake of Hg(II) ions by binding as neutral and chloroanionic species predominate at pH values < 3.0 of a medium rich in chloride ions. A direct and fast batch separation mode was achieved successfully to retain selectively Hg(II) in presence of other eight coexisting metal ions. Thus, Hg(II) was completely retained; Ca(II), Co(II), Ni(II) and Cd(II) were not retained, while Pb(II), Cu(II), Zn(II) and Fe(III) exhibited very low percentage retention evaluated to be 0.42, 0.49, 1.4 and 5.43%, respectively. The utility of the new modified alumina sorbent for concentrating of ultratrace amounts of Hg(ll) was performed by percolating 21 of doubly distilled water, drinking tap water, and Nile river water spiked with lOng/l over 100mg of the sorbent packed in a minicolumn used as a thin layer enrichment bed prior to the determination by CV-AAS. The high recovery values obtained (98.5 +/- 0.5, 98.5 +/- 0.5 and 103.0 +/- 1.0) based on excellent enrichment factor 1000, along with a good precision (R.S.D.% 0.51-0.97%, N= 3) demonstrate the accuracy and validity of the new modified alumina sorbent for preconcentrating ultratrace amounts of Hg(II) with no matrix interference. (c) 2005 Elsevier B.V. All rights reserved.