期刊
TETRAHEDRON LETTERS
卷 47, 期 12, 页码 2021-2023出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.01.048
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The stereoselective synthesis of 2,3-unsaturated alpha-D-glucosides by the S(N)2' addition of diverse aglycones onto 4,6-di-O-benzyl-3-O-propargyl glucal was achieved using a catalytic quantity of AuCl3. The Au catalyzed reaction was explored using various aliphatic, aromatic, alicyclic and monosaccharide aglycones. The current protocol tolerates diverse functional groups and is highly stereoselective, fast, catalytic and mild. (c) 2006 Elsevier Ltd. All rights reserved.
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