期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 128, 期 12, 页码 3974-3979出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja058253l
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The preparation of a series of complexes of the type Cp*IrX2(NHC) provides effective catalysts for the H/D exchange of a wide range of organic molecules in methanol-d(4). The reaction proceeds with higher yields under milder reaction conditions than previous Cp*Ir systems reported thus far. For comparative purposes, we also studied the catalytic activity of Cp*IrCl2(PMe3) under the same reaction conditions. The molecular structures of two of the new Cp*Ir(NHC) complexes are described.
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