期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 348, 期 6, 页码 751-762出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505447
关键词
catalyst immobilization; metathesis; organic-inorganic hybrid materials; ruthenium; sol-gel process
The synthesis of a bis-silylated Hoveyda-type monomer is described as well as the preparation of several organic-inorganic hybrid materials derived from it by a sol-gel process (with and without tetraethyl orthosilicate) and by anchoring to MCM-41. The resulting materials were treated with second generation Grubbs' catalyst to generate second generation Hoveyda-Grubbs-type alkylideneruthenium complexes covalently bonded to the silica matrix. These materials are recyclable catalysts for the ring-closing metathesis reaction of dienes and enynes.
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