期刊
COORDINATION CHEMISTRY REVIEWS
卷 250, 期 7-8, 页码 911-935出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2006.01.017
关键词
uranium; reduction; sterically induced reduction; multi-electron reduction; actinicle; organometaltic; cyclopentadienyl
The U3+ ion offers many opportunities for developing new actinide reaction chemistry. This review surveys the traditional non-aqueous U3+ reduction chemistry in the literature and summarizes recent attempts to combine U3+ reduction with ligand-based reductions to achieve multi-electron reduction with complexes of this ion. The purpose of this analysis is to better identify new possibilities for further expansion of the reduction chemistry of U3+. (c) 2006 Elsevier B.V. All rights reserved.
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