4.7 Article

On the fcc→ monoclinic martensite transformation in a Pu-1.7 at.% Ga alloy

期刊

ACTA MATERIALIA
卷 54, 期 7, 页码 1917-1925

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2005.12.030

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plutonium; crystal structure; martensitic phase transformations; interface defects; dislocation boundaries

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The face-centered cubic delta -> monoclinic alpha' martensite transformation in a Pu-1.7 at.% Ga alloy is analyzed in terms of the defect-based topological model. Disconnections and terrace planes for the transformation are deduced. The predicted habit plane is in good agreement with experimental results. Observed twinning is associated directly with the transformation strain. The lattice invariant deformation is connected with slip in the alpha' plates. Implications for hysteresis ill the transformation as observed by dilatometry and calorimetry are discussed. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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