4.2 Article

Structural and magnetic properties of pure and Ca-doped LaCoO3 nanopowders obtained by a sol-gel route

期刊

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 6, 期 4, 页码 1060-1067

出版社

AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2006.147

关键词

lanthanum cobaltite; Ca-doping; nanopowders; magnetic properties; sol-gel

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Pure and Ca-doped LaCoO3 nanopowders were prepared by a non-alkoxiclic sol-gel route using cobalt(II) acetate, lanthanum(III) nitrate and calcium(II) acetate as oxide precursors. The structural evolution and magnetic properties of the samples were studied as a function of thermal treatments in air up to 1273 K. In particular, the microstructure and composition of the systems were analyzed by X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and X-ray Photoelectron Spectroscopy (XPS). Both pure and calcium-doped samples annealing at 973 K resulted in the formation of cubic LaCoO3 (average crystallite size < 30 nm). This phase was fully retained in the calcium-doped materials even after annealing at higher temperatures, whereas a transition to the rhomboedral polymorph was detected in the pure samples at 1073 K. The magnetic behavior of the nanopowders was investigated as a function of temperature and applied field using both dynamic and static susceptibility measurements. Pure lanthanum cobaltite samples underwent a transition to an ordered state at 88 K, and their magnetic properties changed as a function of thermal treatments. As concerns calcium-doped samples, they ordered ferromagnetically at 171 and 185 K depending on the annealing temperature and displayed open hysteresis loops with coercive fields as large as 1.75 T at low temperatures.

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