期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 348, 期 6, 页码 725-731出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505236
关键词
alkenes; dienes; hydrogen; palladium; silica-supported PAMAM dendrimers
The selective hydrogenation of cyclic and acyclic dienes to monoolefins occurs under very mild conditions, in the presence of silica-supported PAMAM-Pd complexes. The activity and selectivity of this reaction is sensitive to the dendrimer structure. These dendritic complexes display excellent recycle properties, retaining activity for up to eight recycles.
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