First metal azide complex with isonicotinate as a bridging ligand showing new net topology: Hydrothermal synthesis, structure, and magnetic properties

A new 3D azido-bridged coordination polymer, [CO1.5(N-3)(OH)(Isonic)](n) (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology.