期刊
SYNTHESIS-STUTTGART
卷 -, 期 7, 页码 1127-1132出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-926378
关键词
imines; enaminones; erbium triflate; Lewis acids; catalysis
Aldimines, ketimines, and enaminones can be obtained under erbium(III) triflate catalysis. The reaction mechanism is that typical of imine synthesis. The role of the catalyst is demonstrated for the synthesis of aromatic imines. In contrast to CeCl3/NaI addition to unsaturated aldehydes, which results in Michael addition, no Michael adduct was observed under erbium(III) triflate catalysis.
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