Isotope effects on the phase behaviour of cetyltrimethylammonium bromide in H20 and D20 studied by time resolved X-ray diffraction

The liquid-crystalline phases of C(16)TAB/H2O and C(16)TAB/D2O lyotropic systems, at high concentrations (60.0-90.0 wt% surfactant) have been investigated in the temperature range of 30-120 degrees C. Time resolved X-ray diffraction (TRXRD) with synchrotron radiation was applied to record the diffraction spectra at different temperatures over this range. We have obtained highly resolved phase diagrams of the two systems and identified hexagonal, cubic, lamellar and 2D monoclinic (deformed hexagonal) phases. Isotope effects appear when H2O is substituted by D2O at comparable molar concentrations Of surfactant. Particularly where: (1) about 2 degrees C higher (hexagonal-monoclinic) phase transition temperature, and (2) about 25% larger size hexagonal phase at 31 degrees C. The isotope effects were reduced at higher concentrations and at higher temperatures. The swollen of hexagonal phase in DS, i.e. the secondary isotope effects, is induced by the fact that D2O is a more polar solvent than H2O. (c) 2005 Elsevier B.V. All rights reserved.