期刊
JOURNAL OF CHROMATOGRAPHY A
卷 1111, 期 1, 页码 89-96出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chroma.2006.01.101
关键词
pesticides; polycyclic aromatic hydrocarbons; olive oil; olive-pomace oil; gel permeation chromatography; gas chromatography; tandem mass spectrometry
A multiresidue method for determining major pesticides and polycyclic aromatic hydrocarbons (PAHs) in olive oils in a single injection by use of gas chromatography/tandem mass spectrometry (GC-MS/MS) is proposed. Samples are previously extracted with an acetonitrile/n-hexane mixture and cleaned up by gel permeation chromatography. Electron ionization and chemical ionization allow pesticides and PAHs to be determined in a single analysis. The precision obtained was quite satisfactory (relative standard deviations ranged from 3 to 7.8%), and so were recoveries (84-110%). The linear relation was observed from 1 to 500 mu g/kg for pesticides and 0.3 to 200 mu g/kg for PAHs; also, the determination coefficient, R-2, was better than 0.995 in all instances. The proposed method was applied to the routine analysis of PAH and pesticide residues in virgin and refined olive oil and olive-pomace oil samples. (c) 2006 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据