期刊
TETRAHEDRON LETTERS
卷 47, 期 15, 页码 2585-2589出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.02.036
关键词
amine thiourea; asymmetric organocatalysis; Michael addition reaction; nitroolefins; thioacetic acid
A method for organocatalytic, enantioselective Michael addition reactions of thioacetic acid with a range of trans-beta-nitrostyrenes has been developed. The processes, promoted by the chiral amine thiourea organocatalyst, take place in high yields with up to 70% ee. (c) 2006 Elsevier Ltd. All rights reserved.
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