期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2006, 期 8, 页码 1852-1856出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200500914
关键词
olefin cross metathesis; dihydroxylation; hydrogenation; alkaloids; natural products
We report an efficient synthesis of (+)-hyacinthacine A(2) in six steps from (S)-N-Cbz-vinylgylcine. The key strategies were the olefin cross metathesis (CM), Sharpless asymmetric dihydroxylation, and a sequential double reductive cyclization. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).
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