期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 100, 期 2, 页码 1214-1221出版社
WILEY
DOI: 10.1002/app.23466
关键词
poly(ester-anhydride); polycondensation; copolymerization; fluorescence; degradation
In this work, two kinds of diacid monomers were synthesized by a convenient scheme, where 4-hydroxy-3-methoxybenzoic acid (vanillic acid) or 4-hydroxy-3,5-dimethoxybenzoic acid (syringic acid) directly condensated with succinic chloride. Corresponding polyanhydrides were obtained by melt polycondensation. Copolyanhydrides composed of the new monomers and sebacic acid (SA) were further prepared and characterized by NMR, DSC, and fluorometer. The two new kinds of polyanhydride emit strong fluorescence and have similar fluorescent spectra to poly(di(p-carboxyphenyl) succinate anhydride) (P(d-CPS)). The emission wavelength (lambda(em)) of the copolymers could be tuned by the excitation wavelength (lambda(ex)). Degradation rate of the copolyanhydrides decreased as dMOCPS or ddMOCPS fraction increased, and the degradation duration could be modulated from several days to more than 3 months. It addition, the copolyanhydrides displayed typical surface-degradation characteristics. (c) 2006 Wiley Periodicals, Inc.
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