Using high-resolution atomic force microscopy, we have shown extremely high stability of linear ferroelectric domains in epitaxial PbZr0.2Ti0.8O3 thin films heated up to 735 degrees C, a significant advantage for technological applications. An elevated transition temperature similar to 785 degrees C is observed even in relatively thick (91 nm) films, despite relaxation of in-plane film-substrate lattice-mismatch-induced strain. We also demonstrate the negligible role of the film surface in determining the written domain-wall configuration, both by direct comparison of the surface roughness with domain-wall position at successive thermal cycles, and by measurements of domain-wall dynamics before and after heating. (c) 2006 American Institute of Physics.
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