期刊
ADVANCED MATERIALS
卷 18, 期 8, 页码 997-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200501814
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Polydimethylsiloxane-based self-healing is achieved through the tin-catalyzed polycondensation of phase-separated droplets. The catalyst is released into the crack plane when microcapsules containing a tin compound are ruptured by the advancing crack (see figure). This system greatly extends the capability of self-healing polymers by introducing a new, stable healing chemistry into a structural polymer matrix and may provide a route to self-healing in harsh and corrosive environments.
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