期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 128, 期 15, 页码 5127-5135出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja058303m
关键词
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The introduction of bulky substituents at the stereogenic center of light-driven second-generation molecular motors results in an acceleration of the speed of rotation. This is due to a more strained structure with elongated C=C bonds and a higher energy level of the ground state relative to the transition state for the rate-limiting thermal isomerization step. Understanding the profound influence that variation of the substituent at the stereogenic center holds over the rotational speed of the light-driven molecular motor has enabled the development of the fastest molecular motor reported thus far.
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