期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 16, 期 15, 页码 1439-1444出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b515129e
关键词
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The two-photon absorption (TPA) properties of various terpyridines of the kind [4'-(C6H4-(P)-X)2,2':6',2-terpyridine] and related homoleptic and heteroleptic bis(terpyridine) cationic zinc(11) complexes were investigated by the TPA induced photoluminescence (TPA-PL) method in a femtosecond regime. It appeared that terpyridines bearing an X donor group are characterized by TPA cross sections among the largest ever reported for a molecule with a dipole symmetry whereas coordination to a Zn(II) center leads to a decrease of the TPA response.
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