期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 128, 期 16, 页码 5541-5547出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0603204
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The symmetric diacetylenes, 2,4-hexadiynylene dibenzoate 4 and 2,4-hexadiynylene bis(pentafluorobenzoate) 5, as well as the unsymmetric 6-(pentafluorobenzoyloxy)hexa-2,4-diynyl benzoate 6 were prepared and investigated with respect to their reactivity toward topochemical polymerization in the crystalline state. The 1:1 cocrystal 4-5 was successfully polymerized to the corresponding poly(diacetylene) copolymer 7, as evidenced by solid-state C-13 NMR and Raman spectroscopy, as well as single-crystal structure analysis of the monomer-polymer cocrystal. Thus, perfluorophenyl-phenyl interactions were utilized as complementary supramolecular synthons in the cocrystallization of two different diacetylene monomers and their unprecedented conversion into a strictly alternating diacetylene copolymer.
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