期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 9, 页码 3564-3568出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo060250j
关键词
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Using a procedure analogous to that developed for nucleophilic trifluoromethylation, the perfluoroalkyl anion reagents created by mixing C2F5I and n-C4F9I with tetrakis(dimethylamino)ethylene (TDAE) were effective in their nucleophilic reactions with aldehydes, ketones, imines, disulfides, and diselenides. Irradiation proved beneficial in the aldehyde and ketone reactions.
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