期刊
CATALYSIS LETTERS
卷 108, 期 3-4, 页码 179-186出版社
SPRINGER
DOI: 10.1007/s10562-006-0046-6
关键词
xylose; furfural; dehydration; acid catalysis; niobium silicates; microporous; mesoporous
Microporous AM-11 crystalline niobium silicates were studied as solid acid catalysts for the dehydration of xylose in a water-toluene solvent mixture at 140-180 degrees C. After 6 h at 160 degrees C, xylose conversions of up to 90% and furfural yields of up to 50% were achieved, and the catalysts could be reused without loss of activity or selectivity. The calcined AM-11 catalysts gave higher furfural yields than HY zeolite and mordenite, under identical reaction conditions. Ordered mesoporous MCM-41-type niobium silicates with Si/Nb molar ratios of either 25 or 50 were also found to be recyclable catalysts for xylose dehydration, and gave furfural yields consistently in the range of 34-39% (after 6 h reaction at 160 degrees C).
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