Effect of bromide and iodide ions on the formation and speciation of disinfection byproducts during chlorination

Two natural waters were fortified with various levels of bromide or iodide ions (0-30 mu M) and chlorinated in the laboratory to study the impact of bromide and iodide ions on the formation and speciation of disinfection byproducts. Trihalomethanes (THMs), haloacetic acids (HAAS), total organic halogen (TOX), and its halogen-specific fractions total organic chlorine (TOCI), bromine (TOBr), and iodine (TOO, were measured in this work. The molar yields of THMs and HAAS increased as the initial bromide concentration increased. No significant change in TOX concentration was found for varying bromide concentrations. However, TOX concentrations decreased substantially with increasing initial iodide concentrations. At higher levels of bromide, there was a decreasing level of unknown TOX and unknown TOCI but an increasing level of unknown TOBr. The extent of iodine substitution was much lower than that of bromine substitution when comparing identical initial concentrations because a substantial amount of iodide was oxidized to iodate by chlorine. The tendency toward iodate formation resulted in the unusual situation where higher chlorine doses actually caused reduced levels of iodinated organic byproducts. Quantitative assessment of the results of this study showed a good agreement with kinetic data in the literature.