期刊
COORDINATION CHEMISTRY REVIEWS
卷 250, 期 9-10, 页码 1178-1195出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2005.11.023
关键词
group 15 elements; pnicogenido ligands; multiple bonds
A survey of transition-metal complexes with substituent-free Group 15 E-1 ligands of coordination numbers 1 and 2 is presented. Such ligands exhibit interesting bonding properties and diverse reactivity patterns including cycloadditions, redox, and single-atom transfer. The various modes of coordination and relevant aspects to each regarding synthesis, bonding, and reactivity are summarized. (c) 2005 Elsevier B.V. All rights reserved.
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