4.6 Article

Inverse freezing in mean-field models of fragile glasses

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PHYSICAL REVIEW B
卷 73, 期 18, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.73.180202

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A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the random first-order scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favored, an inverse static glass transition and a double inverse dynamic freezing appear.

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