期刊
COORDINATION CHEMISTRY REVIEWS
卷 250, 期 9-10, 页码 991-1011出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2005.12.010
关键词
hydrosilane; silicon; silyl; silylene; platinum; palladium; nickel
This article provides an account of the group 10 transition-metal complexes with metal-silicon bonds formed by the reaction of hydrosilanes with group 10 transition-metal complexes, with particular emphasis on the unique chemistry of 1,2-disilylbenzene, 1-dimethylsilyl-2-silylbenzene and bis(2-silylphenyl)silane. These hydrosilanes provide sterically less congested bidentate and tridentate silyl ligands and make it possible to stabilize a number of unusual mono-, di- and trinuclear poly(silyl) group 10 metal complexes including those of high formal valence state. (c) 2005 Elsevier B.V. All rights reserved.
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