4.3 Review

Charge ordering in organic conductors

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PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.75.051008

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charge order; charge disproportionation; NMR; X-ray; infrared/Raman spectroscopy; (DI-DCNQI)(2)-Ag; (TMTTF)(2)X; alpha-(BEDT-TTF)(2)I-3; theta-(BEDT-TTF)(2)RbZn(SCN)(4)

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Present status of experiments on charge ordering (CO) phenomena observed in organic molecular conductors is reviewed. Experimental techniques to detect and analyze the CO, i.e., NMR, X-ray and Infrared/Raman spectroscopy, are described and the experimental results in typical materials exhibiting CO are summarized. (DI-DCNQI)(2)Ag, (TMTTF)(2)X, alpha-(BEDT-TTF)(2)I-3, theta-(BEDT-TTF)(2)RbZn(SCN)(4) and related materials are discussed. Charge disproportionation without long-range order observed in numbers of materials are also included.

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