Selective catalytic reduction of NOx with NH3 over Cu-ZSM-5 -: The effect of changing the gas composition

The selective catalytic reduction of nitrogen oxides (NOx) with ammonia over ZSM-5 catalysts was studied with and without water vapor. The activity of H-, Na- and Cu-ZSM-5 was compared and the result showed that the activity was greatly enhanced by the introduction of copper ions. A comparison between Cu-ZSM-5 of different silica to alumina ratios was also performed. The highest NO conversion was observed oven the sample with the lowest silica to alumina ratio and the highest copper content. Further studies were performed with the Cu-ZSM-5-27 (silica/alumina = 27) sample to investigate the effect of changes in the feed gas. Oxygen improves the activity at temperatures below 250 degrees C, but at higher temperatures O-2 decreases the activity. The presence of water enhances the NO reduction, especially at high temperature. It is important to use about equal amounts of nitrogen oxides and ammonia at 175 degrees C to avoid ammonia slip and a blocking effect, but also to have high enough concentration to reduce the NOx. At high temperature higher NH3 Concentrations result in additional NOx reduction since more NH3 becomes available for the NO reduction. At these higher temperatures ammonia oxidation increases so that there is no ammonia slip. Exposing the catalyst to equimolecular amounts of NO and NO2 increases the conversion of NOx, but causes an increased formation of N2O. (c) 2005 Elsevier B.V. All rights reserved.